Information card for entry 2216539

Structure parameters

• Chemical name: Di-μ-thiocyanato-bis[bis(tri-<i>p</i>-tolylphosphine)silver(I)] acetonitrile disolvate
• Formula: C90 H90 Ag2 N4 P4 S2
• Calculated formula: C90 H90 Ag2 N4 P4 S2
• SMILES: C1#[N][Ag]([P](c2ccc(cc2)C)(c2ccc(cc2)C)c2ccc(cc2)C)([P](c2ccc(cc2)C)(c2ccc(cc2)C)c2ccc(cc2)C)SC#[N][Ag](S1)([P](c1ccc(cc1)C)(c1ccc(cc1)C)c1ccc(cc1)C)[P](c1ccc(cc1)C)(c1ccc(cc1)C)c1ccc(cc1)C.CC#N.CC#N
• Title of publication: Di-μ-thiocyanato-bis[bis(tri-<i>p</i>-tolylphosphine)silver(I)] acetonitrile disolvate
• Authors of publication: Venter, Gertruida J. S.; Meijboom, Reinout; Roodt, Andreas
• Journal of publication: Acta Crystallographica Section E
• Year of publication: 2007
• Journal volume: 63
• Journal issue: 12
• Pages of publication: m3076 - m3077
• a: 10.8842 ± 0.0005 Å
• b: 13.8418 ± 0.0007 Å
• c: 15.4048 ± 0.0008 Å
• α: 75.839 ± 0.003°
• β: 69.345 ± 0.002°
• γ: 72.833 ± 0.002°
• Cell volume: 2049.11 ± 0.18 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for significantly intense reflections: 0.0427
• Weighted residual factors for all reflections included in the refinement: 0.1212
• Goodness-of-fit parameter for all reflections included in the refinement: 1.033
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes