Information card for entry 2226714

Structure parameters

• Chemical name: (μ-Oxalato-κ^4^<i>O</i>^1^,<i>O</i>^2^:<i>O</i>^1'^,<i>O</i>^2'^)bis[bis(2,2'- bipyridine-κ^2^<i>N</i>,<i>N</i>')cobalt(II)] μ~6~-oxido-dodeca-μ~2~-oxido-hexaoxido-hexatungstate(VI)
• Formula: C42 H32 Co2 N8 O23 W6
• Calculated formula: C42 H32 Co2 N8 O23 W6
• SMILES: c1cccc2c3[n]([Co]45([n]12)([n]1ccccc1c1[n]4cccc1)[O]=C1C(O5)=[O][Co]24([n]5ccccc5c5cccc[n]25)([n]2ccccc2c2[n]4cccc2)O1)cccc3.O=[W]1234O[W]567(O[W]89(O1)(O[W]1%10(O6)(=O)O[W]6(O5)(O2)(=O)O[W]([O]37816)(O%10)(O9)(=O)O4)=O)=O
• Title of publication: (μ-Oxalato-κ^4^<i>O</i>^1^,<i>O</i>^2^:<i>O</i>^1'^,<i>O</i>^2'^)bis[bis(2,2'-bipyridine-κ^2^<i>N</i>,<i>N</i>')cobalt(II)] μ~6~-oxido-dodeca-μ~2~-oxido-hexaoxido-hexatungstate(VI)
• Authors of publication: Shi, Congwen; Fan, Liming; Wei, Peihai; Li, Bin; Zhang, Xiutang
• Journal of publication: Acta Crystallographica Section E
• Year of publication: 2010
• Journal volume: 66
• Journal issue: 7
• Pages of publication: m822 - m823
• a: 9.4876 ± 0.0015 Å
• b: 9.8548 ± 0.0015 Å
• c: 14.174 ± 0.002 Å
• α: 90.769 ± 0.002°
• β: 91.576 ± 0.002°
• γ: 91.113 ± 0.002°
• Cell volume: 1324.4 ± 0.3 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.043
• Residual factor for significantly intense reflections: 0.0309
• Weighted residual factors for significantly intense reflections: 0.0705
• Weighted residual factors for all reflections included in the refinement: 0.0755
• Goodness-of-fit parameter for all reflections included in the refinement: 1.003
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes