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Information card for entry 2227373
Preview
Coordinates | 2227373.cif |
---|---|
Structure factors | 2227373.hkl |
Original IUCr paper | HTML |
Chemical name | tris[μ~2~-bis(diphenylphosphino)methane]- 3:6κ^2^<i>P</i>:<i>P</i>';4:5κ^2^<i>P</i>:<i>P</i>'; 5:6κ^2^<i>P</i>:<i>P</i>'-μ~5~-sulfido-2:3:4:5:6κ^5^<i>S</i>- μ~3~-sulfido-1:3:4κ^3^<i>S</i>- tetra-μ~2~-sulfido-1:3κ^2^<i>S</i>;1:4κ^2^<i>S</i>; 2:5κ^2^<i>S</i>;2:6κ^2^<i>S</i>-disulfido-1κ<i>S</i>,2κ<i>S</i>- tetrasilver(I)ditungsten(VI) <i>N</i>,<i>N</i>-dimethylformamide disolvate |
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Formula | C81 H80 Ag4 N2 O2 P6 S8 W2 |
Calculated formula | C81 H80 Ag4 N2 O2 P6 S8 W2 |
SMILES | [W]12(S[Ag]34[S]1[Ag]1(S2)[S]235[W]3(S[Ag]2([P](c2ccccc2)(c2ccccc2)C[P]1(c1ccccc1)c1ccccc1)[P](C[P]([Ag]5(S3)[P](C[P]4(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)=S)=S.O=CN(C)C.O=CN(C)C |
Title of publication | A tetrasilver(I)ditungsten(VI) cluster with sulfide and bis(diphenylphosphino)methane ligands |
Authors of publication | Wang, Rong; Song, Li-Li; Hu, Ke-Yi; Jin, Qiong-Hua; Zhang, Cun-Lin |
Journal of publication | Acta Crystallographica Section E |
Year of publication | 2010 |
Journal volume | 66 |
Journal issue | 10 |
Pages of publication | m1185 - m1186 |
a | 22.931 ± 0.002 Å |
b | 14.0395 ± 0.0012 Å |
c | 27.855 ± 0.003 Å |
α | 90° |
β | 107.224 ± 0.001° |
γ | 90° |
Cell volume | 8565.5 ± 1.4 Å3 |
Cell temperature | 93 ± 2 K |
Ambient diffraction temperature | 93 ± 2 K |
Number of distinct elements | 8 |
Space group number | 14 |
Hermann-Mauguin space group symbol | P 1 21/c 1 |
Hall space group symbol | -P 2ybc |
Residual factor for all reflections | 0.0417 |
Residual factor for significantly intense reflections | 0.0394 |
Weighted residual factors for significantly intense reflections | 0.0873 |
Weighted residual factors for all reflections included in the refinement | 0.0887 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.142 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | Yes |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/2227373.html
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