Information card for entry 2227373

Structure parameters

• Chemical name: tris[μ~2~-bis(diphenylphosphino)methane]- 3:6κ^2^<i>P</i>:<i>P</i>';4:5κ^2^<i>P</i>:<i>P</i>'; 5:6κ^2^<i>P</i>:<i>P</i>'-μ~5~-sulfido-2:3:4:5:6κ^5^<i>S</i>- μ~3~-sulfido-1:3:4κ^3^<i>S</i>- tetra-μ~2~-sulfido-1:3κ^2^<i>S</i>;1:4κ^2^<i>S</i>; 2:5κ^2^<i>S</i>;2:6κ^2^<i>S</i>-disulfido-1κ<i>S</i>,2κ<i>S</i>- tetrasilver(I)ditungsten(VI) <i>N</i>,<i>N</i>-dimethylformamide disolvate
• Formula: C81 H80 Ag4 N2 O2 P6 S8 W2
• Calculated formula: C81 H80 Ag4 N2 O2 P6 S8 W2
• SMILES: [W]12(S[Ag]34[S]1[Ag]1(S2)[S]235[W]3(S[Ag]2([P](c2ccccc2)(c2ccccc2)C[P]1(c1ccccc1)c1ccccc1)[P](C[P]([Ag]5(S3)[P](C[P]4(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)=S)=S.O=CN(C)C.O=CN(C)C
• Title of publication: A tetrasilver(I)ditungsten(VI) cluster with sulfide and bis(diphenylphosphino)methane ligands
• Authors of publication: Wang, Rong; Song, Li-Li; Hu, Ke-Yi; Jin, Qiong-Hua; Zhang, Cun-Lin
• Journal of publication: Acta Crystallographica Section E
• Year of publication: 2010
• Journal volume: 66
• Journal issue: 10
• Pages of publication: m1185 - m1186
• a: 22.931 ± 0.002 Å
• b: 14.0395 ± 0.0012 Å
• c: 27.855 ± 0.003 Å
• α: 90°
• β: 107.224 ± 0.001°
• γ: 90°
• Cell volume: 8565.5 ± 1.4 ų
• Cell temperature: 93 ± 2 K
• Ambient diffraction temperature: 93 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0417
• Residual factor for significantly intense reflections: 0.0394
• Weighted residual factors for significantly intense reflections: 0.0873
• Weighted residual factors for all reflections included in the refinement: 0.0887
• Goodness-of-fit parameter for all reflections included in the refinement: 1.142
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes