Information card for entry 2229163

Structure parameters

• Chemical name: [μ-Bis(diphenylphosphanyl)methane-1:2κ^2^<i>P</i>:<i>P</i>']nonacarbonyl- 1κ^3^<i>C</i>,2κ^3^<i>C</i>,3κ^3^<i>C</i>-[tris(biphenyl-4-yl)arsane- 3κ<i>As</i>]-<i>triangulo</i>-triruthenium(0)
• Formula: C70 H49 As O9 P2 Ru3
• Calculated formula: C70 H49 As O9 P2 Ru3
• SMILES: [Ru]12([Ru]([Ru]1([As](c1ccc(cc1)c1ccccc1)(c1ccc(cc1)c1ccccc1)c1ccc(cc1)c1ccccc1)(C#[O])(C#[O])C#[O])([P](C[P]2(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)(C#[O])(C#[O])C#[O])(C#[O])(C#[O])C#[O]
• Title of publication: [μ-Bis(diphenylphosphanyl)methane-1:2κ^2^<i>P</i>:<i>P</i>']nonacarbonyl-1κ^3^<i>C</i>,2κ^3^<i>C</i>,3κ^3^<i>C</i>-[tris(biphenyl-4-yl)arsane-3κ<i>As</i>]-<i>triangulo</i>-triruthenium(0)
• Authors of publication: bin Shawkataly, Omar; Khan, Imthyaz Ahmed; Sirat, Siti Syaida; Yeap, Chin Sing; Fun, Hoong-Kun
• Journal of publication: Acta Crystallographica Section E
• Year of publication: 2011
• Journal volume: 67
• Journal issue: 2
• Pages of publication: m216 - m217
• a: 10.8435 ± 0.0007 Å
• b: 12.6134 ± 0.0008 Å
• c: 22.4695 ± 0.0015 Å
• α: 81.029 ± 0.001°
• β: 82.769 ± 0.001°
• γ: 79.265 ± 0.001°
• Cell volume: 2967.6 ± 0.3 ų
• Cell temperature: 100 ± 0.1 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.043
• Residual factor for significantly intense reflections: 0.03
• Weighted residual factors for significantly intense reflections: 0.0739
• Weighted residual factors for all reflections included in the refinement: 0.0849
• Goodness-of-fit parameter for all reflections included in the refinement: 1.11
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes