Information card for entry 2236795

Structure parameters

• Chemical name: [Bis[μ-bis(diphenylphosphino)methane-1:2κ^2^<i>P</i>:<i>P</i>']- bis(nitrito-κ^2^<i>O</i>,<i>O</i>')]disilver(I) acetonitrile disolvate
• Formula: C54 H50 Ag2 N4 O4 P4
• Calculated formula: C54 H50 Ag2 N4 O4 P4
• SMILES: C1[P](c2ccccc2)(c2ccccc2)[Ag]2(ON=[O]2)[P](c2ccccc2)(c2ccccc2)C[P](c2ccccc2)(c2ccccc2)[Ag]2(ON=[O]2)[P]1(c1ccccc1)c1ccccc1.N#CC.N#CC
• Title of publication: [Bis[μ-bis(diphenylphosphino)methane-1:2κ^2^<i>P</i>:<i>P</i>']-bis(nitrito-κ^2^<i>O</i>,<i>O</i>')]disilver(I) acetonitrile disolvate
• Authors of publication: Yang, Xue; Huang, Xu; Qiu, Qi-Ming; Jin, Qiong-Hua; Zhang, Cun-Lin
• Journal of publication: Acta Crystallographica Section E
• Year of publication: 2012
• Journal volume: 68
• Journal issue: 11
• Pages of publication: m1367
• a: 12.139 ± 0.0011 Å
• b: 11.1247 ± 0.0009 Å
• c: 20.035 ± 0.0018 Å
• α: 90°
• β: 95.543 ± 0.001°
• γ: 90°
• Cell volume: 2692.9 ± 0.4 ų
• Cell temperature: 298 ± 2 K
• Ambient diffraction temperature: 298 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0455
• Residual factor for significantly intense reflections: 0.0319
• Weighted residual factors for significantly intense reflections: 0.0783
• Weighted residual factors for all reflections included in the refinement: 0.0897
• Goodness-of-fit parameter for all reflections included in the refinement: 1.074
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes