Information card for entry 2237243

Structure parameters

• Chemical name: Carbonyl{3,3'-di-<i>tert</i>-butyl-5,5'-dimethoxy-2,2'-bis[(4,4,5,5- tetramethyl-1,3,2-dioxaphospholan-2-yl)oxy]biphenyl- κ^2^<i>P</i>,<i>P</i>'}hydrido(triphenylphosphane-κ<i>P</i>)rhodium(I) diethyl ether trisolvate
• Formula: C105 H114 O12 P3 Rh
• Calculated formula: C95 H89 O9.5 P3 Rh
• Title of publication: Carbonyl{3,3'-di-<i>tert</i>-butyl-5,5'-dimethoxy-2,2'-bis[(4,4,5,5-tetramethyl-1,3,2-dioxaphospholan-2-yl)oxy]biphenyl-κ^2^<i>P</i>,<i>P</i>'}hydrido(triphenylphosphane-κ<i>P</i>)rhodium(I) diethyl ether trisolvate
• Authors of publication: Selent, Detlef; Spannenberg, Anke; Börner, Armin
• Journal of publication: Acta Crystallographica Section E
• Year of publication: 2013
• Journal volume: 69
• Journal issue: 1
• Pages of publication: m14
• a: 21.1611 ± 0.0004 Å
• b: 22.1298 ± 0.0004 Å
• c: 22.602 ± 0.0004 Å
• α: 112.345 ± 0.001°
• β: 101.135 ± 0.001°
• γ: 96.757 ± 0.001°
• Cell volume: 9389.9 ± 0.3 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0779
• Residual factor for significantly intense reflections: 0.0532
• Weighted residual factors for significantly intense reflections: 0.141
• Weighted residual factors for all reflections included in the refinement: 0.1523
• Goodness-of-fit parameter for all reflections included in the refinement: 1.046
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes