Information card for entry 2240229

Structure parameters

• Chemical name: Tricarbonyl(<i>N</i>-diphenylphosphanyl-<i>N</i>,<i>N</i>'-diisopropyl-<i>P</i>-phenylphosphonous diamide-κ^2^<i>P</i>,<i>P</i>')cobalt(I) tetracarbonylcobaltate(-I) toluene 0.25-solvate
• Formula: C32.75 H32 Co2 N2 O7 P2
• Calculated formula: C32.75 H32 Co2 N2 O7 P2
• Title of publication: Crystal structure of tricarbonyl(<i>N</i>-diphenylphosphanyl-<i>N</i>,<i>N</i>'-diisopropyl-<i>P</i>-phenylphosphonous diamide-κ^2^<i>P</i>,<i>P</i>')cobalt(I) tetracarbonylcobaltate({-}I) toluene 0.25-solvate
• Authors of publication: Dura, Laura; Spannenberg, Anke; Beweries, Torsten
• Journal of publication: Acta Crystallographica Section E
• Year of publication: 2014
• Journal volume: 70
• Journal issue: 12
• Pages of publication: 533 - 535
• a: 22.1602 ± 0.0006 Å
• b: 12.973 ± 0.0003 Å
• c: 24.7883 ± 0.0006 Å
• α: 90°
• β: 103.933 ± 0.0012°
• γ: 90°
• Cell volume: 6916.6 ± 0.3 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0431
• Residual factor for significantly intense reflections: 0.0381
• Weighted residual factors for significantly intense reflections: 0.0964
• Weighted residual factors for all reflections included in the refinement: 0.0997
• Goodness-of-fit parameter for all reflections included in the refinement: 1.031
• Diffraction radiation wavelength: 1.54178 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: Yes