Information card for entry 2241270

Structure parameters

• Common name: Hexaamminecobalt(II) bistetracarbonylcobaltate(-I)
• Chemical name: Hexaamminecobalt(II) bis[tetracarbonylcobaltate(-I)]
• Formula: C8 H18 Co3 N6 O8
• Calculated formula: C8 H18 Co3 N6 O8
• SMILES: C(#[O])[Co](C#[O])(C#[O])C#[O].[Co]([NH3])([NH3])([NH3])([NH3])([NH3])[NH3].C(#[O])[Co](C#[O])(C#[O])C#[O]
• Title of publication: Crystal structure of [Co(NH~3~)~6~][Co(CO)~4~]~2~
• Authors of publication: Müller, Thomas G.; Kraus, Florian
• Journal of publication: Acta Crystallographica Section E
• Year of publication: 2015
• Journal volume: 71
• Journal issue: 11
• Pages of publication: 1418 - 1420
• a: 9.3679 ± 0.0004 Å
• b: 9.3679 ± 0.0004 Å
• c: 18.3089 ± 0.0018 Å
• α: 90°
• β: 90°
• γ: 120°
• Cell volume: 1391.48 ± 0.16 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 148
• Hermann-Mauguin space group symbol: R -3
• Hall space group symbol: -R 3
• Residual factor for all reflections: 0.0378
• Residual factor for significantly intense reflections: 0.0336
• Weighted residual factors for significantly intense reflections: 0.0861
• Weighted residual factors for all reflections included in the refinement: 0.0895
• Goodness-of-fit parameter for all reflections included in the refinement: 1.075
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes