Information card for entry 2243672

Structure parameters

• Chemical name: (<i>SP</i>-4-2)-<i>cis</i>-Bis[8-(dimethylphosphanyl)quinoline-κ^2^<i>N</i>,<i>P</i>]nickel(II) bis(perchlorate) nitromethane monosolvate
• Formula: C23 H27 Cl2 N3 Ni O10 P2
• Calculated formula: C23 H27 Cl2 N3 Ni O10 P2
• SMILES: [Ni]12([P](c3cccc4ccc[n]1c34)(C)C)[P](c1cccc3ccc[n]2c13)(C)C.Cl(=O)(=O)(=O)[O-].Cl(=O)(=O)(=O)[O-].O=N(=O)C
• Title of publication: Comparison of molecular structures of <i>cis</i>-bis[8-(dimethylphosphanyl)quinoline]nickel(II) and -platinum(II) complex cations
• Authors of publication: Mori, Masatoshi; Suzuki, Takayoshi
• Journal of publication: Acta Crystallographica Section E
• Year of publication: 2020
• Journal volume: 76
• Journal issue: 12
• Pages of publication: 1813 - 1817
• a: 17.8114 ± 0.0013 Å
• b: 8.9398 ± 0.0006 Å
• c: 18.0245 ± 0.0014 Å
• α: 90°
• β: 100.524 ± 0.003°
• γ: 90°
• Cell volume: 2821.8 ± 0.4 ų
• Cell temperature: 188 ± 2 K
• Ambient diffraction temperature: 188 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.051
• Residual factor for significantly intense reflections: 0.0429
• Weighted residual factors for significantly intense reflections: 0.1119
• Weighted residual factors for all reflections included in the refinement: 0.1169
• Goodness-of-fit parameter for all reflections included in the refinement: 1.047
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes