Information card for entry 2311597

Structure parameters

• Common name: [Co(NH3)6][ReF6]
• Chemical name: Tris[hexaamminecobalt(III)] tetraoxidorhenate(VII) tetrakis[hexafluoridorhenate(IV)] hexahydrate
• Formula: Co3 F24 H54 N18 O10 Re5
• Calculated formula: Co3 F24 H54 N18 O10 Re5
• SMILES: [F-][Re](F)(F)(F)(F)[F-].[F-][Re](F)(F)(F)(F)[F-].[NH3][Co]([NH3])([NH3])([NH3])([NH3])[NH3].O=[Re](=O)(=O)[O-].[Re](F)(F)(F)(F)([F-])[F-].O.O.[Co]([NH3])([NH3])([NH3])([NH3])([NH3])[NH3].[Re](F)(F)(F)(F)([F-])[F-].O.O.O.[NH3][Co]([NH3])([NH3])([NH3])([NH3])[NH3].O
• Title of publication: An unexpected rhenium(IV)-rhenium(VII) salt: [Co(NH₃)₆]₃[Re^VIIO₄][Re^IVF₆]₄·6H₂O.
• Authors of publication: Louis-Jean, James; Mariappan Balasekaran, Samundeeswari; Hagenbach, Adelheid; Poineau, Frederic
• Journal of publication: Acta crystallographica. Section E, Crystallographic communications
• Year of publication: 2019
• Journal volume: 75
• Journal issue: Pt 8
• Pages of publication: 1158 - 1161
• a: 15.982 ± 0.003 Å
• b: 15.982 ± 0.003 Å
• c: 29.74 ± 0.005 Å
• α: 90°
• β: 90°
• γ: 120°
• Cell volume: 6579 ± 2 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 148
• Hermann-Mauguin space group symbol: R -3 :H
• Hall space group symbol: -R 3
• Residual factor for all reflections: 0.0417
• Residual factor for significantly intense reflections: 0.0392
• Weighted residual factors for significantly intense reflections: 0.1122
• Weighted residual factors for all reflections included in the refinement: 0.1144
• Goodness-of-fit parameter for all reflections included in the refinement: 1.084
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No