Information card for entry 2312114

Structure parameters

• Common name: Bis(tert-butyldimethylsilyloxy)dioxomolybdenum(2,2'-bipyridyl)
• Chemical name: (2,2'-Bipyridine-κ^2^<i>N</i>,<i>N</i>')-<i>trans</i>-bis(<i>tert</i>-\ butyldimethylsilyloxy)-<i>cis</i>-dioxiomolybdenum(VI)
• Formula: C22 H38 Mo N2 O4 Si2
• Calculated formula: C22 H38 Mo N2 O4 Si2
• Title of publication: Crystal structure of (2,2'-bi-pyridine-κ²<i>N</i>,<i>N</i>')-<i>trans</i>-bis-(<i>tert</i>-butyl-dimethyl-sil-yloxy)-<i>cis</i>-dioxidomolybdenum(VI).
• Authors of publication: Minyaev, Mikhail E.; Vinogradov, Alexander A.; Nifant'ev, Ilya E.; Churakov, Andrei V.
• Journal of publication: Acta crystallographica. Section E, Crystallographic communications
• Year of publication: 2018
• Journal volume: 74
• Journal issue: Pt 7
• Pages of publication: 970 - 972
• a: 8.4027 ± 0.0008 Å
• b: 12.8657 ± 0.0013 Å
• c: 14.4266 ± 0.0014 Å
• α: 113.144 ± 0.002°
• β: 91.133 ± 0.002°
• γ: 105.501 ± 0.002°
• Cell volume: 1368.1 ± 0.2 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0543
• Residual factor for significantly intense reflections: 0.0343
• Weighted residual factors for significantly intense reflections: 0.0686
• Weighted residual factors for all reflections included in the refinement: 0.0747
• Goodness-of-fit parameter for all reflections included in the refinement: 1.007
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes