Information card for entry 4020590

Structure parameters

• Formula: C34 H50 O5 Si
• Calculated formula: C2.47273 H3.63636 O0.363636 Si0.0727273
• SMILES: [Si](c1ccccc1)(OC[C@@H](C)[C@@H]1OC(O[C@H]([C@@H]2COC3(O2)CCCCC3)[C@@H]1C)(C)C)(c1ccccc1)C(C)(C)C
• Title of publication: Double Diastereoselection in Aldol Reactions Mediated by Dicyclohexylchloroborane between Chiral Aldehydes and a Chiral Ethyl Ketone Derived from L-Erythrulose. Synthesis of a C1-C9 Fragment of the Structure of the Antifungal Metabolite Soraphen A~1α~
• Authors of publication: Santiago Díaz-Oltra; Juan Murga; Eva Falomir; Miguel Carda; Gabriel Peris; J. Alberto Marco
• Journal of publication: Journal of Organic Chemistry
• Year of publication: 2005
• Journal volume: 70
• Pages of publication: 8130 - 8139
• a: 15.0425 ± 0.0009 Å
• b: 18.9412 ± 0.0011 Å
• c: 23.4689 ± 0.0014 Å
• α: 90°
• β: 90.167 ± 0.002°
• γ: 90°
• Cell volume: 6686.8 ± 0.7 ų
• Cell temperature: 273 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 4
• Space group number: 4
• Hermann-Mauguin space group symbol: P 1 21 1
• Hall space group symbol: P 2yb
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No