Information card for entry 4021260

Structure parameters

• Formula: C36 H34 Cl2 N4 Ni O8
• Calculated formula: C36 H34 Cl2 N4 Ni O8
• SMILES: [Ni]123[N](=C(c4c(N3C(=O)c3[n]2cccc3)cccc4)C)[C@H](C(=O)O1)[C@@H](c1ccc(Cl)c(Cl)c1)CC(=O)N1C(=O)OC[C@@H]1c1ccccc1.OC.OC
• Title of publication: Virtually Complete Control of Simple and Face Diastereoselectivity in the Michael Addition Reactions between Achiral Equivalents of a Nucleophilic Glycine and (S)- or (R)-3-(E-Enoyl)-4-phenyl-1,3-oxazolidin-2-ones: Practical Method for Preparation of β-Substituted Pyroglutamic Acids and Prolines
• Authors of publication: Vadim A. Soloshonok; Hisanori Ueki; Rohit Tiwari; Chaozhong Cai; Victor J. Hruby
• Journal of publication: Journal of Organic Chemistry
• Year of publication: 2004
• Journal volume: 69
• Pages of publication: 4984 - 4990
• a: 13.416 ± 0.003 Å
• b: 14.882 ± 0.003 Å
• c: 16.949 ± 0.003 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 3384.1 ± 1.1 ų
• Cell temperature: 110 ± 2 K
• Ambient diffraction temperature: 110 ± 2 K
• Number of distinct elements: 6
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No