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Information card for entry 4025525
Preview
Coordinates | 4025525.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C21 H23 O Si |
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Calculated formula | C21 H23 O Si |
SMILES | [Si](C(=C)[C@@H](c1c2c(cc3c1cccc3)cccc2)CO)(C)(C)C |
Title of publication | Palladium-Catalyzed Allylation of Aryl Halides with Homoallyl Alcohols Bearing a Trisubstituted Double Bond: Application to Chirality Transfer from Hydroxylated Carbon to Benzylic One |
Authors of publication | Ryota Wakabayashi; Daishi Fujino; Sayuri Hayashi; Hideki Yorimitsu; Koichiro Oshima |
Journal of publication | Journal of Organic Chemistry |
Year of publication | 2010 |
Journal volume | 75 |
Pages of publication | 4337 - 4343 |
a | 30.054 ± 0.009 Å |
b | 8.076 ± 0.003 Å |
c | 16.13 ± 0.005 Å |
α | 90° |
β | 109.472 ± 0.01° |
γ | 90° |
Cell volume | 3691 ± 2 Å3 |
Cell temperature | 123 ± 2 K |
Ambient diffraction temperature | 123 ± 2 K |
Number of distinct elements | 4 |
Space group number | 5 |
Hermann-Mauguin space group symbol | C 1 2 1 |
Hall space group symbol | C 2y |
Residual factor for all reflections | 0.1073 |
Residual factor for significantly intense reflections | 0.048 |
Weighted residual factors for significantly intense reflections | 0.1149 |
Weighted residual factors for all reflections included in the refinement | 0.17 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.153 |
Diffraction radiation wavelength | 0.71075 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
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The link is: https://www.crystallography.net/4025525.html
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