Acid catalyzed cyclodimerization of 2,2-bis(trifluoromethyl)-4-alkoxy-oxetanes and -thietanes. Synthesis of 2,2,6,6-tetrakis(trifluoromethyl)-4,8-dialkoxy-1,5-dioxocanes and 3,3,7,7-tetrakis(trifluoromethyl)-9-oxa-2,6-dithia-bicyclo[3.3.1]nonane.
Authors of publication
Petrov, Viacheslav A.; Marshall, Will
Journal of publication
Beilstein journal of organic chemistry
Year of publication
2010
Journal volume
6
Pages of publication
46
a
10.243 ± 0.004 Å
b
5.633 ± 0.002 Å
c
15.676 ± 0.006 Å
α
90°
β
94.912 ± 0.005°
γ
90°
Cell volume
901.2 ± 0.6 Å3
Cell temperature
293 ± 2 K
Ambient diffraction temperature
293 ± 2 K
Number of distinct elements
4
Space group number
13
Hermann-Mauguin space group symbol
P 1 2/n 1
Hall space group symbol
-P 2yac
Residual factor for all reflections
0.0493
Residual factor for significantly intense reflections
0.0349
Weighted residual factors for significantly intense reflections
0.0847
Weighted residual factors for all reflections included in the refinement
0.0927
Goodness-of-fit parameter for all reflections included in the refinement
