Acid catalyzed cyclodimerization of 2,2-bis(trifluoromethyl)-4-alkoxy-oxetanes and -thietanes. Synthesis of 2,2,6,6-tetrakis(trifluoromethyl)-4,8-dialkoxy-1,5-dioxocanes and 3,3,7,7-tetrakis(trifluoromethyl)-9-oxa-2,6-dithia-bicyclo[3.3.1]nonane.
Authors of publication
Petrov, Viacheslav A.; Marshall, Will
Journal of publication
Beilstein journal of organic chemistry
Year of publication
2010
Journal volume
6
Pages of publication
46
a
21.271 ± 0.006 Å
b
25.685 ± 0.007 Å
c
10.563 ± 0.003 Å
α
90°
β
90°
γ
90°
Cell volume
5771 ± 3 Å3
Cell temperature
293 ± 2 K
Ambient diffraction temperature
293 ± 2 K
Number of distinct elements
5
Space group number
68
Hermann-Mauguin space group symbol
C c c a :2
Hall space group symbol
-C 2a 2ac
Residual factor for all reflections
0.0402
Residual factor for significantly intense reflections
0.0308
Weighted residual factors for significantly intense reflections
0.0745
Weighted residual factors for all reflections included in the refinement
0.0825
Goodness-of-fit parameter for all reflections included in the refinement
