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Information card for entry 4035435
Preview
Coordinates | 4035435.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C24 H36 O3 Si |
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Calculated formula | C24 H36 O3 Si |
SMILES | [Si](C1=C(OC)[C@H]2[C@@]([C@@H](C[C@@](C1=O)(C2=O)CC=C)CC=C)(C)CCC=C)(C)(C)C.[Si](C1=C(OC)[C@@H]2[C@]([C@H](C[C@](C1=O)(C2=O)CC=C)CC=C)(C)CCC=C)(C)(C)C |
Title of publication | Modular Total Syntheses of Hyperforin, Papuaforins A, B, and C via Gold(I)-Catalyzed Carbocyclization. |
Authors of publication | Bellavance, Gabriel; Barriault, Louis |
Journal of publication | The Journal of organic chemistry |
Year of publication | 2018 |
Journal volume | 83 |
Journal issue | 13 |
Pages of publication | 7215 - 7230 |
a | 10.585 ± 0.0005 Å |
b | 15.1637 ± 0.0007 Å |
c | 15.7734 ± 0.0007 Å |
α | 73.285 ± 0.003° |
β | 85.172 ± 0.003° |
γ | 89.787 ± 0.003° |
Cell volume | 2415.6 ± 0.2 Å3 |
Cell temperature | 200 ± 2 K |
Ambient diffraction temperature | 200 ± 2 K |
Number of distinct elements | 4 |
Space group number | 2 |
Hermann-Mauguin space group symbol | P -1 |
Hall space group symbol | -P 1 |
Residual factor for all reflections | 0.1225 |
Residual factor for significantly intense reflections | 0.0742 |
Weighted residual factors for significantly intense reflections | 0.1603 |
Weighted residual factors for all reflections included in the refinement | 0.1833 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.066 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/4035435.html
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Users of the data should acknowledge the original authors of the
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