Information card for entry 4060140

Structure parameters

• Formula: C31 H48 Li O P Si2
• Calculated formula: C31 H48 Li O P Si2
• Title of publication: eta5- Rh(I) Complexes of a lamba4-Phosphinine anion: Syntheses, X-ray Crystal Structures and Application in the Catalyzed Hydroformylation of Olefins
• Authors of publication: A. Moores; N. Mezaiiles; L. Ricard; P. Le Floch
• Journal of publication: Organometallics
• Year of publication: 2005
• a: 10.101 ± 0.005 Å
• b: 18.754 ± 0.005 Å
• c: 34.757 ± 0.005 Å
• α: 90 ± 0.005°
• β: 94.11 ± 0.005°
• γ: 90 ± 0.005°
• Cell volume: 6567 ± 4 ų
• Cell temperature: 150 ± 1 K
• Ambient diffraction temperature: 150 ± 1 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0798
• Residual factor for significantly intense reflections: 0.0559
• Weighted residual factors for significantly intense reflections: 0.1468
• Weighted residual factors for all reflections included in the refinement: 0.1649
• Goodness-of-fit parameter for all reflections included in the refinement: 1.032
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No