Information card for entry 4060275

Structure parameters

• Formula: C79 H130 N12 Na4 P6 Sn2
• Calculated formula: C79 H130 N12 Na4 P6 Sn2
• SMILES: [Sn]12P(c3ccccc3)[P]([Na]34([N](C)(C)CC[N]3(C)CC[N]4(C)C)[P]2([Sn]2[P]1(c1ccccc1)[Na]13([N](C)(C)CC[N]1(C)CC[N]3(C)C)[P](P2c1ccccc1)(c1ccccc1)[Na]12[N](C)(C)CC[N]1(C)CC[N]2(C)C)c1ccccc1)(c1ccccc1)[Na]12[N](C)(C)CC[N]1(C)CC[N]2(C)C.c1(ccccc1)C
• Title of publication: Reactions of Sn(NMe~2~)~2~ with Primary Aryl Phosphides, ArPH-: Synthesis and Structures of the Heteroleptic Cages [{(PhP‒PPh)Sn(μ-PPh)}~2~(Na·PMDETA)~4~ and [{Sn(μ~3~-Ppy)}~3~{Sn(μ~3~,μ~1~-pyP‒Ppy)}~3~]
• Authors of publication: García, Felipe; Hopkins, Alexander D.; Kowenicki, Richard A.; McPartlin, Mary; Pask, Christopher M.; Stead, Matthew L.; Woods, Anthony D.; Wright, Dominic S.
• Journal of publication: Organometallics
• Year of publication: 2005
• Journal volume: 24
• Journal issue: 8
• Pages of publication: 1813 - 1818
• a: 22.058 ± 0.004 Å
• b: 18.543 ± 0.004 Å
• c: 25.931 ± 0.005 Å
• α: 90°
• β: 109.2 ± 0.03°
• γ: 90°
• Cell volume: 10017 ± 3 ų
• Cell temperature: 180 ± 2 K
• Ambient diffraction temperature: 180 ± 2 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No