Information card for entry 4060505

Structure parameters

• Formula: C44 H86 Ir2 N2 P2 Si4
• Calculated formula: C44 H86 Ir2 N2 P2 Si4
• SMILES: [Ir]12([Ir]3([P](C(C)C)(C(C)C)C(C)C)([NH]1c1cccc4cccc([NH]23)c14)=C=C([Si](C)(C)C)[Si](C)(C)C)([P](C(C)C)(C(C)C)C(C)C)=C=C([Si](C)(C)C)[Si](C)(C)C
• Title of publication: Reactions of Diamidonaphthalene-Bridged Diiridium Tetrahydride with Alkynes: Hydrogenation, Vinylidene Formation, and Catalytic C-C Coupling
• Authors of publication: Jimenez, M. V.; Sola, E.; Lahoz, F. J.; Oro, L. A.
• Journal of publication: Organometallics
• Year of publication: 2005
• Journal volume: 24
• Journal issue: 11
• Pages of publication: 2722 - 2729
• a: 12.0806 ± 0.0011 Å
• b: 14.202 ± 0.0013 Å
• c: 16.3161 ± 0.0014 Å
• α: 87.897 ± 0.002°
• β: 77.029 ± 0.002°
• γ: 84.659 ± 0.002°
• Cell volume: 2715.7 ± 0.4 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No