Information card for entry 4060669

Structure parameters

• Formula: C25 H55 Li2 N4 P S Si2
• Calculated formula: C25 H55 Li2 N4 P S Si2
• Title of publication: Sterically Controlled Mono- or Dimetalation of a Thioether-Functionalized Phosphine and an Unusual Light-Induced Phosphide-Thiolate Rearrangement
• Authors of publication: Stuart Blair; Keith Izod; Ross W. Harrington; William Clegg
• Journal of publication: Organometallics
• Year of publication: 2003
• Journal volume: 22
• Pages of publication: 302 - 308
• a: 9.6026 ± 0.0005 Å
• b: 11.7841 ± 0.0006 Å
• c: 16.6685 ± 0.0009 Å
• α: 103.822 ± 0.002°
• β: 92.896 ± 0.002°
• γ: 107.49 ± 0.002°
• Cell volume: 1731.58 ± 0.16 ų
• Cell temperature: 160 ± 2 K
• Ambient diffraction temperature: 160 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0475
• Residual factor for significantly intense reflections: 0.0381
• Weighted residual factors for significantly intense reflections: 0.0945
• Weighted residual factors for all reflections included in the refinement: 0.0997
• Goodness-of-fit parameter for all reflections included in the refinement: 1.057
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No