Information card for entry 4060805

Structure parameters

• Common name: trans-[Iodo(bis(bis(diphenylphosphino)ethane) (η^1^pentamethylcyclopentadienylgermylidyne)tungsten(0)
• Formula: C69 H71 Ge I P4 W
• Calculated formula: C69 H71 Ge I P4 W
• SMILES: C1(C(=C(C(=C1C)C)C)C)(C)[Ge][W]12(I)([P](CC[P]1(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)[P](CC[P]2(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1.c1(ccccc1)C
• Title of publication: Molybdenum and Tungsten Germylyne Complexes of the general formula trans-[X(dppe)~2~M≡Ge-(η^1^-Cp^*^)] (X = Cl, Br, I; dppe = Ph~2~PCH~2~CH~2~PPh~2~; Cp^*^ = C~5~Me~5~); Syntheses, Molecular Structures and Bonding Features of the Germylyne Ligand
• Authors of publication: Filippou, Alexander C.; Portius, Peter; Philippopoulos, Athanassios I.
• Journal of publication: Organometallics
• Year of publication: 2002
• a: 10.592 ± 0.002 Å
• b: 16.287 ± 0.003 Å
• c: 17.928 ± 0.003 Å
• α: 97.24 ± 0.02°
• β: 96.58 ± 0.02°
• γ: 103.31 ± 0.02°
• Cell volume: 2952.8 ± 1 ų
• Cell temperature: 180 ± 2 K
• Ambient diffraction temperature: 180 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No