Information card for entry 4060980

Structure parameters

• Formula: C20 H26 B F4 O2 Rh
• Calculated formula: C20 H26 B F4 O2 Rh
• SMILES: [Rh]12345([O]=C([C@H]6[C@@H]7C=C[C@H]([C@@H]56)C7)C)(C#[O])[c]5([c]4([c]3([c]2([c]15C)C)C)C)C.[B](F)(F)(F)[F-].[Rh]12345([O]=C([C@@H]6[C@H]7C=C[C@@H]([C@H]56)C7)C)(C#[O])[c]5([c]4([c]3([c]2([c]15C)C)C)C)C.[B](F)(F)(F)[F-]
• Title of publication: Facile Alkene Insertion into a Rhodium(III)‒Acetyl Bond: Potential Catalysts for CO/Alkene Copolymerization
• Authors of publication: Haynes, Anthony; Haslam, Claire E.; Bonnington, Kevin J.; Parish, Louise; Adams, Harry; Spey, Sharon E.; Marder, Todd B.; Coventry, David N.
• Journal of publication: Organometallics
• Year of publication: 2004
• Journal volume: 23
• Journal issue: 25
• Pages of publication: 5907 - 5909
• a: 32.942 ± 0.017 Å
• b: 15.15 ± 0.008 Å
• c: 8.584 ± 0.005 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 4284 ± 4 ų
• Cell temperature: 298 ± 2 K
• Ambient diffraction temperature: 298 ± 2 K
• Number of distinct elements: 6
• Space group number: 33
• Hermann-Mauguin space group symbol: P n a 21
• Hall space group symbol: P 2c -2n
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No