Information card for entry 4061009

Structure parameters

• Formula: C25 H25 B F4 O3 Ru2 Si2
• Calculated formula: C25 H25 B F4 O3 Ru2 Si2
• SMILES: [Ru]123456([Ru]789%10([CH]1=Cc1ccccc1)(C#[O])[c]1%11[cH]%10[cH]9[cH]8[c]7%11[Si]([c]75[cH]4[cH]3[cH]2[c]67[Si]1(C)C)(C)C)(C#[O])C#[O].[B](F)(F)(F)[F-]
• Title of publication: New Mechanism for the Intermolecular Hydroamination of Alkynes: Catalysis by Dinuclear Ruthenium Complexes with a Rigid Dicyclopentadienyl Ligand
• Authors of publication: Klein, David P.; Ellern, Arkady; Angelici, Robert J.
• Journal of publication: Organometallics
• Year of publication: 2004
• Journal volume: 23
• Journal issue: 24
• Pages of publication: 5662 - 5670
• a: 9.28 ± 0.01 Å
• b: 12.903 ± 0.014 Å
• c: 12.147 ± 0.013 Å
• α: 90°
• β: 108.389 ± 0.017°
• γ: 90°
• Cell volume: 1380 ± 3 ų
• Cell temperature: 193 ± 2 K
• Ambient diffraction temperature: 193 ± 2 K
• Number of distinct elements: 7
• Space group number: 4
• Hermann-Mauguin space group symbol: P 1 21 1
• Hall space group symbol: P 2yb
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No