Information card for entry 4061103

Structure parameters

• Formula: C22 H21 Cl3 Ga P
• Calculated formula: C22 H21 Cl3 Ga P
• SMILES: [Ga](Cl)(Cl)(Cl)[P](=C(c1ccccc1)c1ccccc1)c1c(cc(cc1C)C)C
• Title of publication: Destiny of Transient Phosphenium Ions Generated from the Addition of Electrophiles to Phosphaalkenes: Intramolecular C‒H Activation, Donor‒Acceptor Formation, and Linear Oligomerization
• Authors of publication: Tsang, Chi-Wing; Rohrick, Crystal A.; Saini, Tejindra S.; Patrick, Brian O.; Gates, Derek P.
• Journal of publication: Organometallics
• Year of publication: 2004
• Journal volume: 23
• Journal issue: 25
• Pages of publication: 5913 - 5923
• a: 9.882 ± 0.001 Å
• b: 10.263 ± 0.002 Å
• c: 12.204 ± 0.002 Å
• α: 108.054 ± 0.005°
• β: 94.76 ± 0.003°
• γ: 103.022 ± 0.004°
• Cell volume: 1130.8 ± 0.2 ų
• Cell temperature: 173.2 K
• Ambient diffraction temperature: 173.2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No