Information card for entry 4061141

Structure parameters

• Formula: C39 H63 O8 P2 Rb
• Calculated formula: C39 H63 O8 P2 Rb
• SMILES: P(=C([P-]c1c(cc(cc1C)C)C)C(C)(C)C)c1c(cc(cc1C)C)C.[Rb]123456([O]7CC[O]1CC[O]2CC[O]3CC7)[O]1CC[O]4CC[O]5CC[O]6CC1
• Title of publication: Synthesis and Characterization of 1,3-Diphosphapropene and Alkali-Metal 1,3-Diphosphaallyl Complexes and Unexpected 1,3-Rearrangement of a Cesium 1,3-Diphosphaallyl Complex to a Cesium Secondary Phosphanide
• Authors of publication: Liddle, Stephen T.; Izod, Keith
• Journal of publication: Organometallics
• Year of publication: 2004
• Journal volume: 23
• Journal issue: 23
• Pages of publication: 5550 - 5559
• a: 14.6026 ± 0.0013 Å
• b: 12.1852 ± 0.0011 Å
• c: 23.654 ± 0.002 Å
• α: 90°
• β: 101.095 ± 0.002°
• γ: 90°
• Cell volume: 4130.2 ± 0.6 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No