Information card for entry 4061375

Structure parameters

• Common name: H4Ru4(CO)10(BINAP)
• Formula: C54 H36 O10 P2 Ru4
• Calculated formula: C54 H36 O10 P2 Ru4
• SMILES: C(#[O])[Ru]12345(C#[O])[H][Ru]675(C#[O])(C#[O])(C#[O])[H][Ru]536(C#[O])(C#[O])([H]1)([H][Ru]475(C#[O])(C#[O])C#[O])[P](c1c(c3ccccc3cc1)c1c(ccc3ccccc13)[P]2(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1
• Title of publication: Reaction of (S)-BINAP with H~4~Ru~4~(CO)~12~. The First Example of Face-Bridging BINAP Coordination and 100% Stereoselectivity in Formation of a Chiral Tetranuclear Cluster Framework
• Authors of publication: Tunik, Sergey P.; Pilyugina, Tatiana S.; Koshevoy, Igor O.; Selivanov, Stanislav I.; Haukka, Matti; Pakkanen, Tapani A.
• Journal of publication: Organometallics
• Year of publication: 2004
• Journal volume: 23
• Journal issue: 3
• Pages of publication: 568 - 579
• a: 14.0399 ± 0.0002 Å
• b: 22.1665 ± 0.0003 Å
• c: 47.2933 ± 0.0006 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 14718.4 ± 0.3 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No