Information card for entry 4061378

Structure parameters

• Formula: C95 H77 B N4 O4 P4 Rh4
• Calculated formula: C95 H77 B N4 O4 P4 Rh4
• SMILES: [Rh]1234([Rh]567([Rh]89([P](Cc%10[n]8[n]3c(c%10)C[P]2(c2ccccc2)c2ccccc2)(c2ccccc2)c2ccccc2)([C]47([Rh]21([P](Cc1[n]2[n]6c(c1)C[P]5(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)C#[O])=[CH]9c1ccc(cc1)C)C#[O])C#[O])C#[O].c1(ccccc1)[B-](c1ccccc1)(c1ccccc1)c1ccccc1
• Title of publication: Tetranuclear Complexes Based on a Dynamic Metal-Metal Linkage, [(μ~4~-X)Rh~4~(CO)~4~(PNNP)~2~]^n+^ (X/n = RC⋮C/1 (Acetylide), C~2~/0 (Dicarbide))
• Authors of publication: Tanaka, Shukichi; Dubs, Christian; Inagaki, Akiko; Akita, Munetaka
• Journal of publication: Organometallics
• Year of publication: 2004
• Journal volume: 23
• Journal issue: 3
• Pages of publication: 317 - 319
• a: 17.9746 ± 0.0003 Å
• b: 27.7046 ± 0.0006 Å
• c: 16.6001 ± 0.0003 Å
• α: 90°
• β: 90.846 ± 0.001°
• γ: 90°
• Cell volume: 8265.6 ± 0.3 ų
• Cell temperature: 213.2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/a 1
• Hall space group symbol: -P 2yab
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No