Information card for entry 4061425

Structure parameters

• Formula: C48 H42 F6 N4 P Rh
• Calculated formula: C48 H42 F6 N4 P Rh
• SMILES: [Rh]12345[NH]([C@H]([C@H](c6ccccc6)[NH]1C1c6ccccc6[CH]4=[CH]2c2ccccc12)c1ccccc1)C1c2c([CH]3=[CH]5c3c1cccc3)cccc2.[P](F)(F)(F)(F)(F)[F-].N#CC.N#CC
• Title of publication: Chiral Rhodium(I) and Iridium(I) Amino-Olefin Complexes: pK~a~, N–H Bond Dissociation Energy, and Catalytic Transfer Hydrogenation
• Authors of publication: Maire, Pascal; Breher, Frank; Schönberg, Hartmut; Grützmacher, Hansjörg
• Journal of publication: Organometallics
• Year of publication: 2005
• Journal volume: 24
• Journal issue: 13
• Pages of publication: 3207 - 3218
• a: 10.9913 ± 0.0007 Å
• b: 17.388 ± 0.0012 Å
• c: 22.5209 ± 0.0015 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 4304.1 ± 0.5 ų
• Cell temperature: 200 ± 2 K
• Ambient diffraction temperature: 200 ± 2 K
• Number of distinct elements: 6
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No