Information card for entry 4061899

Structure parameters

• Formula: C46 H59 P2 Rh
• Calculated formula: C46 H59 P2 Rh
• SMILES: [Rh]1234(=Pc5c(cc(cc5C(C)(C)C)C(C)(C)C)C(C)(C)C)([P](c5ccccc5)(c5ccccc5)c5ccccc5)[c]5([c]4([c]3([c]2([c]15C)C)C)C)C
• Title of publication: Terminal Phosphinidene Complexes Cp^R^(L)M=PAr of the Group 9 Transition Metals Co, Rh, and Ir. Synthesis, Structures, and Properties
• Authors of publication: Termaten, Arjan T.; Aktas, Halil; Schakel, Marius; Ehlers, Andreas W.; Lutz, Martin; Spek, Anthony L.; Lammertsma, Koop
• Journal of publication: Organometallics
• Year of publication: 2003
• a: 9.7539 ± 0.0001 Å
• b: 14.3652 ± 0.0002 Å
• c: 16.8717 ± 0.0002 Å
• α: 64.9564 ± 0.0007°
• β: 78.5027 ± 0.0007°
• γ: 72.699 ± 0.0008°
• Cell volume: 2037.47 ± 0.04 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 4
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No