Information card for entry 4061903

Structure parameters

• Formula: C27 H26 B N6 O2 Rh
• Calculated formula: C27 H26 B N6 O2 Rh
• SMILES: [Rh]1([n]2n(c(C)cc2c2ccccc2)[BH]([n]2[n]1c(cc2C)C)[n]1[n]c(cc1C)c1ccccc1)(C#[O])C#[O]
• Title of publication: Complexes of Heteroscorpionate Trispyrazolylborate Ligands. Part X. Structures and Fluxional Behavior of Rhodium(I) Complexes with Heteroscorpionate Trispyrazolylborate Ligands, Tp”Rh(LL); (LL) = (CO)2 or (COD)
• Authors of publication: Ruman, Tomasz; Ciunik, Zbigniew; Trzeciak, Anna M.; Wołowiec, Stanisław; Ziółkowski, Józef J.
• Journal of publication: Organometallics
• Year of publication: 2003
• Journal volume: 22
• Journal issue: 5
• Pages of publication: 1072 - 1080
• a: 12.6077 ± 0.0007 Å
• b: 19.6436 ± 0.001 Å
• c: 11.212 ± 0.0007 Å
• α: 90°
• β: 105.554 ± 0.005°
• γ: 90°
• Cell volume: 2675.1 ± 0.3 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No