Information card for entry 4062324

Structure parameters

• Formula: C74 H64 Cl12 Fe2 O2 P4 Ru2
• Calculated formula: C74 H64 Cl12 Fe2 O2 P4 Ru2
• SMILES: [c]123[cH]4[cH]5[cH]6[cH]1[Fe]17893456[c]3([cH]1[cH]7[cH]8[cH]93)[P](c1ccccc1)(c1ccccc1)[Ru]1([P]2(c2ccccc2)c2ccccc2)(C#[O])([Cl][Ru]2([P]([c]34[cH]5[cH]6[cH]7[cH]3[Fe]389%104567[c]4([cH]3[cH]8[cH]9[cH]%104)[P]2(c2ccccc2)c2ccccc2)(c2ccccc2)c2ccccc2)(C#[O])([Cl]1)Cl)Cl.C(Cl)Cl.C(Cl)Cl.C(Cl)Cl.C(Cl)Cl
• Title of publication: An Easy Entry to Dimers [{RuX(μ-X)(CO)(P⌒P)}2] (X = Cl, Br; P⌒P = 1,1‘-Bis(diphenylphosphino)ferrocene, 1,1‘-Bis(diisopropylphosphino)ferrocene) from η^3^-Allyl-Ruthenium(II) Derivatives [RuX(η^3^-2-C3H4R)(CO)(P⌒P)] (R = H, Me): Efficient Catalyst Precursors in Transfer Hydrogenation of Ketones
• Authors of publication: Cadierno, Victorio; Crochet, Pascale; Díez, Josefina; García-Garrido, Sergio E.; Gimeno, José
• Journal of publication: Organometallics
• Year of publication: 2003
• Journal volume: 22
• Journal issue: 25
• Pages of publication: 5226 - 5234
• a: 12.3336 ± 0.0007 Å
• b: 12.7635 ± 0.0007 Å
• c: 13.2492 ± 0.0008 Å
• α: 90.154 ± 0.004°
• β: 103.397 ± 0.003°
• γ: 113.446 ± 0.003°
• Cell volume: 1850.86 ± 0.18 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No