Information card for entry 4062449

Structure parameters

• Formula: C22 H31 N O2 Si W
• Calculated formula: C22 H31 N O2 Si W
• SMILES: [W]12345(C#[O])(C#[O])(c6ccccc6[N+]([Si]5(C)C)(C)C)[c]5([c]1([c]2([c]3([c]45C)C)C)C)C
• Title of publication: Facile Isomerization of a Tungsten Silyl Complex to a Base-Stabilized Silylene Complex via 1,2-Migration of an Aryl Group
• Authors of publication: Okazaki, Masaaki; Suzuki, Eiji; Miyajima, Norito; Tobita, Hiromi; Ogino, Hiroshi
• Journal of publication: Organometallics
• Year of publication: 2003
• Journal volume: 22
• Journal issue: 23
• Pages of publication: 4633 - 4635
• a: 10.61 ± 0.001 Å
• b: 15.18 ± 0.001 Å
• c: 13.4861 ± 0.0009 Å
• α: 90°
• β: 94.782 ± 0.005°
• γ: 90°
• Cell volume: 2164.6 ± 0.3 ų
• Cell temperature: 150.2 K
• Number of distinct elements: 6
• Space group number: 9
• Hermann-Mauguin space group symbol: C 1 c 1
• Hall space group symbol: C -2yc
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No