Crystallography Open Database
- COD Home
- Accessing COD Data
- Add Your Data
- Documentation
Information card for entry 4063955
Preview
Coordinates | 4063955.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C36 H52 O2 Os P2 |
---|---|
Calculated formula | C36 H52 O2 Os P2 |
SMILES | [Os]12345678(/C(=C\C(=O)C)P9(=O)[C]2(=[CH]3[CH]4=[C]19C1CCCCC1)C1CCCCC1)P1[C]5(=[CH]8[CH]7=[C]61C1CCCCC1)C1CCCCC1 |
Title of publication | Preparation of Osmium η5-Phospholide Complexes and Their Reactions with Acyl Electrophiles: C═O Bond Cleavage and C−C Bond Formation within the Metal Coordination Sphere |
Authors of publication | Ogasawara, Masamichi; Shintani, Minoru; Watanabe, Susumu; Sakamoto, Takeshi; Nakajima, Kiyohiko; Takahashi, Tamotsu |
Journal of publication | Organometallics |
Year of publication | 2011 |
Journal volume | 30 |
Journal issue | 6 |
Pages of publication | 1487 |
a | 10.7091 ± 0.0002 Å |
b | 25.2803 ± 0.0005 Å |
c | 12.6928 ± 0.0002 Å |
α | 90° |
β | 102.921 ± 0.0007° |
γ | 90° |
Cell volume | 3349.3 ± 0.11 Å3 |
Cell temperature | 298.1 K |
Ambient diffraction temperature | 298 K |
Number of distinct elements | 5 |
Space group number | 14 |
Hermann-Mauguin space group symbol | P 1 21/c 1 |
Hall space group symbol | -P 2ybc |
Residual factor for significantly intense reflections | 0.0457 |
Weighted residual factors for all reflections included in the refinement | 0.0962 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.074 |
Diffraction radiation wavelength | 0.71075 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/4063955.html
All data in the COD and the database itself are dedicated to the
public domain and licensed under the
CC0
License
.
Users of the data should acknowledge the original authors of the
structural data.