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Information card for entry 4064012
Preview
Coordinates | 4064012.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C42 H48 Cl N2 O P Pd Pt |
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Calculated formula | C42 H48 Cl N2 O P Pd Pt |
SMILES | [Pd]12(=C([C@@H](C)c3ccccc3[C@H](C)[N]2(C)C)[P@]2([Pt]3(c4c(c5c(cc4)cccc5)[C@@H](C)[N]3(C)C)[O]=C([C@@H]12)C)c1ccccc1)Cl.c1ccccc1 |
Title of publication | Asymmetric Synthesis of P-Stereogenic Homo- and Heterobimetallic Complexes via Selective Monoinsertion of Dialkynylphosphine into the Pd−C Bond of a Palladacycle |
Authors of publication | Chen, Shuli; Pullarkat, Sumod A.; Li, Yongxin; Leung, Pak-Hing |
Journal of publication | Organometallics |
Year of publication | 2011 |
Journal volume | 30 |
Journal issue | 6 |
Pages of publication | 1530 |
a | 9.7661 ± 0.0004 Å |
b | 19.072 ± 0.0007 Å |
c | 10.6031 ± 0.0004 Å |
α | 90° |
β | 103.175 ± 0.002° |
γ | 90° |
Cell volume | 1922.94 ± 0.13 Å3 |
Cell temperature | 103 ± 2 K |
Ambient diffraction temperature | 103 ± 2 K |
Number of distinct elements | 8 |
Space group number | 4 |
Hermann-Mauguin space group symbol | P 1 21 1 |
Hall space group symbol | P 2yb |
Residual factor for all reflections | 0.0243 |
Residual factor for significantly intense reflections | 0.0205 |
Weighted residual factors for significantly intense reflections | 0.0498 |
Weighted residual factors for all reflections included in the refinement | 0.0891 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.061 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
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The link is: https://www.crystallography.net/4064012.html
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