Information card for entry 4064036

Structure parameters

• Formula: C22 H34 Cl5 Ru2 S Sb
• Calculated formula: C22 H34 Cl5 Ru2 S Sb
• SMILES: [Sb]12([Cl][Ru]345678([Ru]9%10%11%12([Cl]1)([Cl]3)([S]24)[c]1([c]9([c]%10([c]%11([c]%121C)C)C)C)CC)[c]1([c]5([c]6([c]7([c]81C)C)C)C)CC)(Cl)Cl
• Title of publication: Preparation of Incomplete Cubane-Type Ru2M(μ3-S)(μ2-Cl)3Clusters (M = Sb, Bi) and Isolation of the Ru2Sb Cluster Having a Novel μ3-SO Ligand. Functions in Oxygen Atom Transfer and Catalytic Oxidation of PPh3to O═PPh3by Molecular O2
• Authors of publication: Oya, Kazumasa; Seino, Hidetake; Akiizumi, Midori; Mizobe, Yasushi
• Journal of publication: Organometallics
• Year of publication: 2011
• Journal volume: 30
• Journal issue: 11
• Pages of publication: 2939
• a: 10.759 ± 0.003 Å
• b: 13.574 ± 0.004 Å
• c: 19.806 ± 0.005 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 2892.5 ± 1.4 ų
• Cell temperature: 293.1 K
• Ambient diffraction temperature: 293.1 K
• Number of distinct elements: 6
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for significantly intense reflections: 0.046
• Weighted residual factors for all reflections included in the refinement: 0.1107
• Goodness-of-fit parameter for all reflections included in the refinement: 1.035
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No