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Information card for entry 4064147
Preview
Coordinates | 4064147.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C33 H35 F6 N3 O P Rh |
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Calculated formula | C33 H35 F6 N3 O P Rh |
SMILES | [Rh]12345([CH]6=[CH]1c1c([CH]2=[CH]3c2c6cccc2)cccc1)[n]1c(cccc1C)C[NH]5Cc1cccc(C)[n]41.[P](F)(F)(F)(F)(F)[F-].C(=O)(C)C |
Title of publication | Open-Shell Organometallic [MII(dbcot(bislutidylamine)]2+Complexes (M = Rh, Ir): Unexpected Base-Assisted Reduction of the Metal Instead of Amine Ligand Deprotonation |
Authors of publication | Dzik, Wojciech I.; Fuente Arruga, Luis; Siegler, Maxime A.; Spek, Anthony L.; Reek, Joost N. H.; de Bruin, Bas |
Journal of publication | Organometallics |
Year of publication | 2011 |
Journal volume | 30 |
Journal issue | 7 |
Pages of publication | 1902 |
a | 28.5187 ± 0.0008 Å |
b | 11.2036 ± 0.0003 Å |
c | 19.4833 ± 0.0004 Å |
α | 90° |
β | 101.351 ± 0.001° |
γ | 90° |
Cell volume | 6103.4 ± 0.3 Å3 |
Cell temperature | 110 ± 2 K |
Ambient diffraction temperature | 110 ± 2 K |
Number of distinct elements | 7 |
Space group number | 9 |
Hermann-Mauguin space group symbol | C 1 c 1 |
Hall space group symbol | C -2yc |
Residual factor for all reflections | 0.0368 |
Residual factor for significantly intense reflections | 0.0281 |
Weighted residual factors for significantly intense reflections | 0.0569 |
Weighted residual factors for all reflections included in the refinement | 0.06 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.047 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
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The link is: https://www.crystallography.net/4064147.html
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