Information card for entry 4064486

Structure parameters

• Formula: C22 H29 N Si2
• Calculated formula: C22 H29 N Si2
• SMILES: [Si]1([C@H]([C@H]([SiH](C)C)c2n(c3c(c12)cccc3)C)c1ccc(cc1)C)(C)C.[Si]1([C@@H]([C@@H]([SiH](C)C)c2n(c3c(c12)cccc3)C)c1ccc(cc1)C)(C)C
• Title of publication: 2-Vinylindoles As the Four-Atom Component in a Catalytic [4+1] Cycloaddition with a Silylene-Palladium Species Generated from (Aminosilyl)boronic Ester
• Authors of publication: Masuda, Kohei; Ohmura, Toshimichi; Suginome, Michinori
• Journal of publication: Organometallics
• Year of publication: 2011
• Journal volume: 30
• Journal issue: 6
• Pages of publication: 1322
• a: 14.5564 ± 0.0005 Å
• b: 8.1265 ± 0.0002 Å
• c: 19.5917 ± 0.0006 Å
• α: 90°
• β: 112.229 ± 0.001°
• γ: 90°
• Cell volume: 2145.32 ± 0.11 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 4
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/a 1
• Hall space group symbol: -P 2yab
• Residual factor for all reflections: 0.0451
• Residual factor for significantly intense reflections: 0.0349
• Weighted residual factors for significantly intense reflections: 0.0882
• Weighted residual factors for all reflections included in the refinement: 0.094
• Goodness-of-fit parameter for all reflections included in the refinement: 1.039
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No