Information card for entry 4064521

Structure parameters

• Formula: C36 H44 P2 Pt Si
• Calculated formula: C36 H44 P2 Pt Si
• SMILES: [Pt]1(C(=C[Si](C=C1c1ccc(cc1)C)(c1ccccc1)c1ccccc1)c1ccc(cc1)C)([P](C)(C)C)[P](C)(C)C
• Title of publication: Dinuclear Palladium and Platinum Complexes with Bridging Silylene Ligands. Preparation Using (Aminosilyl)boronic Ester as the Ligand Precursor and Their Reactions with Alkynes
• Authors of publication: Tanabe, Makoto; Jiang, Jian; Yamazawa, Hideto; Osakada, Kohtaro; Ohmura, Toshimichi; Suginome, Michinori
• Journal of publication: Organometallics
• Year of publication: 2011
• Journal volume: 30
• Journal issue: 15
• Pages of publication: 3981
• a: 20.1864 ± 0.0006 Å
• b: 15.5085 ± 0.0003 Å
• c: 21.8311 ± 0.0006 Å
• α: 90°
• β: 92.6084 ± 0.0017°
• γ: 90°
• Cell volume: 6827.4 ± 0.3 ų
• Cell temperature: 113 K
• Ambient diffraction temperature: 113 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0597
• Residual factor for significantly intense reflections: 0.0439
• Weighted residual factors for significantly intense reflections: 0.1137
• Weighted residual factors for all reflections included in the refinement: 0.1536
• Goodness-of-fit parameter for all reflections included in the refinement: 1.099
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No