Information card for entry 4065817

Structure parameters

• Formula: C62 H62 B F24 P2 Rh
• Calculated formula: C62 H62 B F24 P2 Rh
• Title of publication: Isolation of a Low-Coordinate Rhodium Phosphine Complex Formed by C−C Bond Activation of Biphenylene
• Authors of publication: Chaplin, Adrian B.; Tonner, Ralf; Weller, Andrew S.
• Journal of publication: Organometallics
• Year of publication: 2010
• Journal volume: 29
• Journal issue: 12
• Pages of publication: 2710
• a: 20.4586 ± 0.0002 Å
• b: 12.6672 ± 0.0001 Å
• c: 24.9881 ± 0.0003 Å
• α: 90°
• β: 99.6886 ± 0.0005°
• γ: 90°
• Cell volume: 6383.38 ± 0.11 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0778
• Residual factor for significantly intense reflections: 0.0543
• Weighted residual factors for significantly intense reflections: 0.1369
• Weighted residual factors for all reflections included in the refinement: 0.1534
• Goodness-of-fit parameter for all reflections included in the refinement: 1.015
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No