Information card for entry 4065883

Structure parameters

• Common name: [Rh(dippe)(mu-S-3-MeC12H8)]2 (5)
• Formula: C54 H86 P4 Rh2 S2
• Calculated formula: C54 H86 P4 Rh2 S2
• Title of publication: Carbon−Sulfur Bond Activation of Dibenzothiophenes and Phenoxythiin by [Rh(dippe)(μ-H)]2and [Rh2(dippe)2(μ-Cl)(μ-H)]†
• Authors of publication: Oster, Stephen S.; Grochowski, Matthew R.; Lachicotte, Rene J.; Brennessel, William W.; Jones, William D.
• Journal of publication: Organometallics
• Year of publication: 2010
• Journal volume: 29
• Journal issue: 21
• Pages of publication: 4923
• a: 20.2048 ± 0.0014 Å
• b: 15.6941 ± 0.0011 Å
• c: 16.7713 ± 0.0012 Å
• α: 90°
• β: 96.491 ± 0.002°
• γ: 90°
• Cell volume: 5284 ± 0.6 ų
• Cell temperature: 100 ± 0.1 K
• Ambient diffraction temperature: 100 ± 0.1 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.123
• Residual factor for significantly intense reflections: 0.0554
• Weighted residual factors for significantly intense reflections: 0.1016
• Weighted residual factors for all reflections included in the refinement: 0.1275
• Goodness-of-fit parameter for all reflections included in the refinement: 0.976
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No