Information card for entry 4066090

Structure parameters

• Formula: C18 H37 N O2 Si2 W
• Calculated formula: C18 H37 N O2 Si2 W
• SMILES: C(N1O[W]23451(C[Si](C)(C)C)([c]1([c]5([c]4([c]3([c]21C)C)C)C)C)=O)[Si](C)(C)C
• Title of publication: Hydroperoxide-Initiated Intramolecular Insertions of NO into Metal−Carbon Bonds†
• Authors of publication: Graham, Peter M.; Buschhaus, Miriam S. A.; Baillie, Rhett A.; Semproni, Scott P.; Legzdins, Peter
• Journal of publication: Organometallics
• Year of publication: 2010
• Journal volume: 29
• Journal issue: 21
• Pages of publication: 5068
• a: 9.9833 ± 0.0009 Å
• b: 10.6781 ± 0.001 Å
• c: 12.7497 ± 0.0011 Å
• α: 110.998 ± 0.004°
• β: 111.235 ± 0.004°
• γ: 95.911 ± 0.004°
• Cell volume: 1139.64 ± 0.19 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0184
• Residual factor for significantly intense reflections: 0.0172
• Weighted residual factors for significantly intense reflections: 0.0408
• Weighted residual factors for all reflections included in the refinement: 0.0412
• Goodness-of-fit parameter for all reflections included in the refinement: 1.121
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No