Information card for entry 4066352

Structure parameters

• Formula: C27 H59 Rh Si3
• Calculated formula: C27 H59 Rh Si3
• SMILES: C[Si](C)(C(C)(C)C)[c]12[c]3(C)[c]4(C)[c]5([c]1(C)[RhH2]2345([Si](CC)(CC)CC)[Si](CC)(CC)CC)C
• Title of publication: Synthesis of Rhodium Complexes with Bulky Substituted Cyclopentadienyl Ligands. H/D Exchange Reactions and Silane Activation†
• Authors of publication: Esqueda, Ana Cristina; Conejero, Salvador; Maya, Celia; Carmona, Ernesto
• Journal of publication: Organometallics
• Year of publication: 2010
• Journal volume: 29
• Journal issue: 21
• Pages of publication: 5481
• a: 10.415 ± 0.0006 Å
• b: 10.5078 ± 0.0006 Å
• c: 15.705 ± 0.0008 Å
• α: 88.196 ± 0.002°
• β: 84.251 ± 0.003°
• γ: 67.076 ± 0.002°
• Cell volume: 1574.98 ± 0.15 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 4
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0385
• Residual factor for significantly intense reflections: 0.0341
• Weighted residual factors for significantly intense reflections: 0.1086
• Weighted residual factors for all reflections included in the refinement: 0.1128
• Goodness-of-fit parameter for all reflections included in the refinement: 1.03
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No