Information card for entry 4066655

Structure parameters

• Formula: C18 H28 N P2 V
• Calculated formula: C18 H28 N P2 V
• Title of publication: Thermolysis of Half-Sandwich Vanadium(V) Imido Complexes to Generate Vanadium(III) Imido Species via a Vanadium(IV) Intermediate
• Authors of publication: Batinas, Aurora A.; Dam, Jeroen; Meetsma, Auke; Hessen, Bart; Bouwkamp, Marco W.
• Journal of publication: Organometallics
• Year of publication: 2010
• Journal volume: 29
• Journal issue: 23
• Pages of publication: 6230
• a: 10.404 ± 0.001 Å
• b: 10.939 ± 0.001 Å
• c: 17.404 ± 0.002 Å
• α: 90°
• β: 95.317 ± 0.002°
• γ: 90°
• Cell volume: 1972.2 ± 0.3 ų
• Cell temperature: 100 ± 1 K
• Ambient diffraction temperature: 100 ± 1 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0656
• Residual factor for significantly intense reflections: 0.0489
• Weighted residual factors for significantly intense reflections: 0.1086
• Weighted residual factors for all reflections included in the refinement: 0.115
• Goodness-of-fit parameter for all reflections included in the refinement: 1.054
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No