Information card for entry 4066912

Structure parameters

• Formula: C34 H28 Cl4 N2 P2 Pd Sn
• Calculated formula: C34 H28 Cl4 N2 P2 Pd Sn
• SMILES: [Sn]12([Pd](Cl)([P](c3ccccc3)(c3ccccc3)c3[n]1cccc3)[P](c1ccccc1)(c1ccccc1)c1[n]2cccc1)(Cl)(Cl)Cl
• Title of publication: Oxidative Addition of Sn−C Bonds on Palladium(0): Identification of Palladium−Stannyl Species and a Facile Synthetic Route to Diphosphinostannylene−Palladium Complexes
• Authors of publication: Cabon, Yves; Reboule, Irena; Lutz, Martin; Klein Gebbink, Robertus J. M.; Deelman, Berth-Jan
• Journal of publication: Organometallics
• Year of publication: 2010
• Journal volume: 29
• Journal issue: 22
• Pages of publication: 5904
• a: 14.4729 ± 0.0006 Å
• b: 12.5944 ± 0.0013 Å
• c: 22.8027 ± 0.0011 Å
• α: 90°
• β: 124.973 ± 0.002°
• γ: 90°
• Cell volume: 3405.9 ± 0.4 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0573
• Residual factor for significantly intense reflections: 0.0338
• Weighted residual factors for significantly intense reflections: 0.0678
• Weighted residual factors for all reflections included in the refinement: 0.076
• Goodness-of-fit parameter for all reflections included in the refinement: 1.035
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No