Information card for entry 4067187

Structure parameters

• Formula: C14 H32 Cl4 Ni P2 Si
• Calculated formula: C14 H32 Cl4 Ni P2 Si
• SMILES: [Ni]1(Cl)([P](CC[P]1(C(C)C)C(C)C)(C(C)C)C(C)C)[Si](Cl)(Cl)Cl
• Title of publication: Dehydrocoupling of Organosilanes with a Dinuclear Nickel Hydride Catalyst and Isolation of a Nickel Silyl Complex
• Authors of publication: Smith, Erin E.; Du, Guodong; Fanwick, Phillip E.; Abu-Omar, Mahdi M.
• Journal of publication: Organometallics
• Year of publication: 2010
• Journal volume: 29
• Journal issue: 23
• Pages of publication: 6527
• a: 8.8414 ± 0.0004 Å
• b: 13.6132 ± 0.0005 Å
• c: 18.7005 ± 0.0008 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 2250.79 ± 0.16 ų
• Cell temperature: 150 K
• Ambient diffraction temperature: 150 K
• Number of distinct elements: 6
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.046
• Residual factor for significantly intense reflections: 0.033
• Weighted residual factors for significantly intense reflections: 0.066
• Weighted residual factors for all reflections included in the refinement: 0.07
• Goodness-of-fit parameter for all reflections included in the refinement: 1.007
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MO-Kα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No