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Information card for entry 4067776
Preview
Coordinates | 4067776.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C36 H41 N O2 Si W |
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Calculated formula | C36 H41 N O2 Si W |
SMILES | [W]12345([N](=C1CC)[Si](c1ccc(cc1)C)(c1ccc(cc1)C)c1ccc(cc1)C)(C#[O])(C#[O])[c]1([c]2([c]3([c]4([c]51C)C)C)C)C |
Title of publication | Synthesis and Characterization of κ2C,N-N-Silyliminoacyl Tungsten Complexes Cp*(CO)2W{κ2C,N-C(R)═NSiR′3} [R = Me, Et,i-Pr,t-Bu; R′3= (p-Tol)2Me, (p-Tol)3, Et3; Cp* = η5-C5Me5]: Thermally Induced Carbon−Carbon Bond Cleavage of Their Iminoacyl Ligands |
Authors of publication | Suzuki, Eiji; Komuro, Takashi; Kanno, Yuto; Okazaki, Masaaki; Tobita, Hiromi |
Journal of publication | Organometallics |
Year of publication | 2010 |
Journal volume | 29 |
Journal issue | 7 |
Pages of publication | 1839 |
a | 9.0675 ± 0.0003 Å |
b | 14.7448 ± 0.0004 Å |
c | 24.3446 ± 0.0008 Å |
α | 90° |
β | 91.9946 ± 0.001° |
γ | 90° |
Cell volume | 3252.86 ± 0.18 Å3 |
Cell temperature | 150 ± 2 K |
Ambient diffraction temperature | 150 ± 2 K |
Number of distinct elements | 6 |
Space group number | 14 |
Hermann-Mauguin space group symbol | P 1 21/c 1 |
Hall space group symbol | -P 2ybc |
Residual factor for all reflections | 0.0585 |
Residual factor for significantly intense reflections | 0.0505 |
Weighted residual factors for significantly intense reflections | 0.1397 |
Weighted residual factors for all reflections included in the refinement | 0.1582 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.132 |
Diffraction radiation wavelength | 0.71069 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
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