Information card for entry 4067932

Structure parameters

• Formula: C27 H53 F3 O3 P3 Rh S Si
• Calculated formula: C27 H53 F3 O3 P3 Rh S Si
• SMILES: [Rh]12345([P@](C[Si](C)(C[P@@]1(C(C)(C)C)C)C[P@@]2(C(C)(C)C)C)(C(C)(C)C)C)[CH]1=[CH]3C2[CH]4=[CH]5C1C2.S(=O)(=O)([O-])C(F)(F)F
• Title of publication: Asymmetric Synthesis and Metal Complexes of aC3-Symmetric P-Stereogenic Triphosphine, (R)-MeSi(CH2PMe(t-Bu))3(MT-Siliphos)
• Authors of publication: Cain, Matthew F.; Glueck, David S.; Golen, James A.; Rheingold, Arnold L.
• Journal of publication: Organometallics
• Year of publication: 2012
• Journal volume: 31
• Journal issue: 3
• Pages of publication: 775
• a: 9.7734 ± 0.0003 Å
• b: 11.6223 ± 0.0004 Å
• c: 15.3027 ± 0.0005 Å
• α: 88.046 ± 0.002°
• β: 74.705 ± 0.001°
• γ: 82.959 ± 0.001°
• Cell volume: 1664.01 ± 0.09 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 8
• Space group number: 1
• Hermann-Mauguin space group symbol: P 1
• Hall space group symbol: P 1
• Residual factor for all reflections: 0.0303
• Residual factor for significantly intense reflections: 0.0284
• Weighted residual factors for significantly intense reflections: 0.0706
• Weighted residual factors for all reflections included in the refinement: 0.0721
• Goodness-of-fit parameter for all reflections included in the refinement: 1.036
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No