Information card for entry 4068105

Structure parameters

• Formula: C44.5 H81 N4 Nd Si4
• Calculated formula: C44.5 H77 N4 Nd Si4
• Title of publication: Synthesis of Dianionic β-Diketiminate Lanthanide Amides L′LnN(SiMe3)2(THF) by Deprotonation of the β-Diketiminate Ligand L (L = {[(2,6-iPr2C6H3)NC(CH3)]2CH}−) and the Transformation with [HNEt3][BPh4] to the Cationic Samarium Amide [LSmN(SiMe3)2][BPh4]
• Authors of publication: Liu, Peng; Zhang, Yong; Yao, Yingming; Shen, Qi
• Journal of publication: Organometallics
• Year of publication: 2012
• Journal volume: 31
• Journal issue: 3
• Pages of publication: 1017
• a: 11.7324 ± 0.0003 Å
• b: 11.7814 ± 0.0002 Å
• c: 20.5952 ± 0.0006 Å
• α: 75.163 ± 0.003°
• β: 79.407 ± 0.003°
• γ: 68.293 ± 0.003°
• Cell volume: 2544.08 ± 0.12 ų
• Cell temperature: 223 ± 2 K
• Ambient diffraction temperature: 223 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0337
• Residual factor for significantly intense reflections: 0.0303
• Weighted residual factors for significantly intense reflections: 0.0764
• Weighted residual factors for all reflections included in the refinement: 0.0793
• Goodness-of-fit parameter for all reflections included in the refinement: 1.064
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No