Information card for entry 4068180

Structure parameters

• Formula: C24 H44 Ge Mo N2 O2 Si3
• Calculated formula: C24 H44 Ge Mo N2 O2 Si3
• SMILES: C([Si](C)(C)C)([Si](C)(C)C)([Si](C)(C)C)[Ge](=C1N(C(=C(C)N1C)C)C)[Mo]1234([cH]5[cH]4[cH]3[cH]2[cH]15)(C#[O])C#[O]
• Title of publication: Metal Activation of a Germylenoid, a New Approach to Metal‒Germanium Triple Bonds: Synthesis and Reactions of the Germylidyne Complexes [Cp(CO)2M≡Ge‒C(SiMe3)3] (M = Mo, W)
• Authors of publication: Filippou, Alexander C.; Stumpf, Kai W.; Chernov, Oleg; Schnakenburg, Gregor
• Journal of publication: Organometallics
• Year of publication: 2012
• Journal volume: 31
• Journal issue: 2
• Pages of publication: 748
• a: 9.4339 ± 0.0003 Å
• b: 20.2764 ± 0.0011 Å
• c: 15.1795 ± 0.0006 Å
• α: 90°
• β: 90.68 ± 0.003°
• γ: 90°
• Cell volume: 2903.4 ± 0.2 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0713
• Residual factor for significantly intense reflections: 0.0442
• Weighted residual factors for significantly intense reflections: 0.0735
• Weighted residual factors for all reflections included in the refinement: 0.0791
• Goodness-of-fit parameter for all reflections included in the refinement: 0.964
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No